Applied mineral exploration methods, hydrothermal fluids, baro-acoustic decrepitation, CO2 rich fluids
Viewpoints:

How CO2 inclusions form from aqueous fluids

Understanding heterogeneous fluids : why gold is not transported in CO2 fluids

Gold-quartz deposits form from aqueous heterogeneous fluids: NOT from CO2 fluids

Inclusion shapes can prove heterogeneous FI trapping

Disproportional FI trapping from heterogeneous fluids explains gas-dominant systems

A discussion of H2 analysis by mass spectrometry

A mechanism to form H2 in the MS ioniser during analyses


News:

Sangan skarn Fe deposits, Iran

New model 205 decreptiometer

Studies of 6 Pegmatite deposits

A study of the Gejiu tin mine, China


Exploration using palaeo-hydrothermal fluids

Using opaque minerals to understand ore fluids


Understanding baro-acoustic decrepitation.

An introduction to fluid inclusions and mineral exploration applications.



 Interesting Conferences:


AGCC expo, Adelaide, Aust. Oct. 14-18 2018

-----2019-----

ECROFI, June 24-26, Budapest, Hungary

AOGS, Singapore, 28 Jul-2 Aug 2019

SGA, Glasgow Scotland, Aug. 27-30 2019


Comprehensive Geology Conference Calendar


Baro-acoustic decrepitation analyses at the Cukuralan Au mine, Turkey

Samples collected during ECROFI field trip visit, June 2013


The Study

After the ECROFI 22 conference (2013) the Cukuralan Au mine was visited. The opportunity was taken to collect samples for baro-acoustic decrepitation analysis to compare the fluid inclusion assemblages from this deposit with that of many other gold deposits shown elsewhere on this website.

Conclusions

There are too few sample locations in this brief study to draw broad conclusions. However it is clear that baro-acoustic decrepitation can be applied to this type of deposit, although the mixed quartz and feldspar samples make interpretation difficult. There are several distinctly different decrepitation signatures which could assist in identifying different hydrothermal phases, most notably the barren quartz veins which seem to be a late stage overprint of the system. None of the samples had low temperature decrepitation which indicates that CO2 was absent or only a minor constituent of the hydrothermal fluid system.

Geological Background

The following geological information is from the ECROFI 22 field trip guide, 2013 by Huseyin Ozturk & Zeynep Cansu.

Location


cukuralan location map

The Çukuralan Au deposit is in the Bergama (İzmir) region of western Turkey. The deposit is a low sulphidation epithermal deposit (similar to the Ovacık-Au deposit (40 km southeast of Çukuralan) occurring within the porphyritic dykes that cut the local metamorphic sequence known as Karakaya Complex. The gold grade varies between 0.5 and 50g/T, with mining from an open pit.

Mineralisation at Cukuralan is related to porphyry dykes which were formed at the same time as the tectonics which caused ductile deformation. It is uncertain if the gold is derived by leaching of the regional Permian aged metamorphics during later Miocene aged magmatic events. It is thought that the mineralisation is related to the intrusion of porphyry dykes. The gold deposition is primarily lithologically controlled by reducing host rocks, but deposition also occurs without lithological control. Quartz, and calcite occur as gangue minerals. The mineralisation is structurally controlled and occurs along 2 different fault systems oriented NE-SW (younger) and NW-SE (older).

The baro-acoustic decrepitation study

Samples

Samples were collected from the unoxidized ore zone and also from the adjacent oxidized ore zone. At each sample location multiple sub-samples were collected within a few metres radius and these were analysed individually. Samples from the same location are plotted together on the following graphs. The samples were mostly of porphyry rather than quartz. An additional sample from a barren quartz vein in the footwall was collected from about 30 metres away. During sample preparation 2 samples (2219C and 2219D) were treated with dilute HCl to dissolve carbonates which were present.


Unoxidized ore zone

Only sub-sample 2219D was predominantly of quartz and the other sub-samples were of porphyry and also contained feldspar. This mineral mixture has probably caused a complex decrepitation pattern and contributes to the unusually high decrepitation at 600 C on sub-samples 2219A, 2219B and 2219D. The lack of decrepitation below 350 C indicates that there was little or no CO2 in the hydrothermal fluids.


cukuralan ore zone results

Oxidized ore zone

Samples from the oxidized ore zone are not clearly different from those in the unoxidized ore zone and again they lack CO2. Sample 2220E was visually distinct and was of cherty silica rather than milky feldspar-silica. This sample had almost no decrepitation as is typical for chert. Sub-sample 2220D also had no decrepitation and is probably also chert.

cukuralan 30m from ore


Barren quartz in the footwall


This quartz sample has similar character to the quartz sub-sample 2219D (above) from within the unoxidized ore zone. It suggests that the quartz veining may be a late stage barren overprint and that the gold mineralisation is part of a separate event, possibly more closely associated with the porphyry. There is no evidence of CO2 in this fluids in this sample.

cukuralan results footwall barren quartz

Summary

Many samples show broad decrepitation from 350 C to over 600 C, which is possibly because of the presence of both feldspar and quartz in the samples. The samples which were only of quartz (2219D and 2221) show decrepitation from 350 C to about 550 C. These quartz veins may be a late stage overprint on the mineralisation. None of the samples shows a low temperature decrepitation peak (around 250 C to 350C) which is typical of CO2-rich fluids, and the hydrothermal fluids at Cukuralan seem to lack significant content of CO2.

Sample 2220E was seen to be of chert and had almost no decrepitation, which is typical for chert samples. Sample 2220D also had no decrepitation and may also be a chert. There does not seem to be any significant difference between the unoxidized ore (sample 2219) and the oxidized ore (sample 2220) zones, which is as expected for a supergene oxidation event.


The sample descriptions are here


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