Applied mineral exploration methods, hydrothermal fluids, baro-acoustic decrepitation, CO2 rich fluids
Viewpoints:

How CO2 inclusions form from aqueous fluids

Understanding heterogeneous fluids : why gold is not transported in CO2 fluids

Gold-quartz deposits form from aqueous heterogeneous fluids: NOT from CO2 fluids

Inclusion shapes can prove heterogeneous FI trapping

Disproportional FI trapping from heterogeneous fluids explains gas-dominant systems

A discussion of H2 analysis by mass spectrometry

A mechanism to form H2 in the MS ioniser during analyses


News:

Sangan skarn Fe deposits, Iran

New model 205 decreptiometer

Studies of 6 Pegmatite deposits

A study of the Gejiu tin mine, China


Exploration using palaeo-hydrothermal fluids

Using opaque minerals to understand ore fluids


Understanding baro-acoustic decrepitation.

An introduction to fluid inclusions and mineral exploration applications.



 Interesting Conferences:


AGCC expo, Adelaide, Aust. Oct. 14-18 2018

-----2019-----

ECROFI, June 24-26, Budapest, Hungary

AOGS, Singapore, 28 Jul-2 Aug 2019

SGA, Glasgow Scotland, Aug. 27-30 2019


Comprehensive Geology Conference Calendar


Brusson area Au, NW Italy

A Baro-acoustic decrepitation study on a well documented mine

Introduction

The Brusson area of North-western Italy hosts several gold mines which have been worked since roman times. These have also been the focus of intensive recent research by L.W. Diamond and others. The quartz veins occur in brittle fracture structures within gneiss and marble host rocks, but gold only occurs in the quartz veins within the gneiss host rock. The Fluids which formed the auriferous quartz veins were of metamorphic origin during the alpine orogen and Diamond has determined time constraints on the fluid processes suggesting that hydrothermal activity lasted less than 2 Ma.

37 samples were collected from the Fenilia mine area for baro-acoustic decrepitation. Because the mine adits were inaccessible, the samples came from dump material at each of 3 adit entrances at different mine levels as well as surface quartz outcrop from the overlying carbonate.

The mine is located in the north-western alps of Italy in Val d'Ayas.

brusloc


The sample locations were recorded using a GPS. Samples came from adit entrances and mining dump waste on the hillside at 4 different levels.

gpslocs


The cross section shows the lower levels of the Fenilia vein hosted by paragneiss. These levels are auriferous. At the uppermost level 4, the Fenilia vein is hosted within carbonate rocks and is now barren of gold. Past studies have tried, unsuccessfully, to explain the lack of gold in the Fenilia quartz vein where it is hosted by carbonate. 


brusson section


Brusson decrepitation results

Samples were collected from adit entrances on 4 levels of the Brusson mine, specifically including the uppermost level which is hosted by carbonate rocks and is considered to be barren of Au.

Each site is allocated a single sample number, at which multiple quartz fragments were collected over several metres radius and the quartz is from unknown locations within the adjacent adit. Each fragment is allocated an alphabetic suffix and analysed separately, with different “RUN” numbers.

Before analysis each quartz fragment was briefly described to see if there was a correlation between visible quartz characteristics and decrepitation response.

The sample details are listed here. The locations were fixed by GPS and waypoint names IT6 – IT9 are these positions and are plotted on the topography map.

In addition, several samples from nearby areas were collected as “background” quartz, but there were few opportunities to collect such background samples.

Interpretation

The complete decrepitation analyses for all these samples are shown in the plots later in this page. Low temperature decrepitation peaks indicative of high CO2 contents in the inclusion fluids are common, but there are variations which do not relate to quartz hand sample description or presumed Au content. In particular, the top level samples (H2053-H2056, sample 1957) are not obviously different to samples from the lower levels which are considered to be auriferous. Most, but not all the samples have a low Temp Peak due to CO2/CH4 rich fluids.

Some of the samples from the 2 nearby background areas also show CO2 so it seems that CO2 content alone does not relate closely to Au content at Brusson. Or perhaps the CO2 anomaly halo around mineralisation is so large that all the quartz in this region is within the anomaly.

At first inspection, the initial plot of all samples together, colour coded by mine level and shown here,  does not distinguish between the lower auriferous levels and the uppermost level 4 barren sample. 

All brusson results

However, plotting this data using a special logarithmic y axis to accentuate  the important region from 20 to 500 counts reveals that there are 3 distinct types of quartz. Type 1 quartz has high levels of contained CO2. Type 2 quartz has lesser, but still substantial, levels of CO2. Type 3 quartz lacks CO2 rich fluid inclusions. In the following plot these groups are distinguished and a scatter plot (inset) of quartz types versus mine level shows that there is no type-3 quartz at the uppermost mine level.

So the decrepitation data DOES distinguish a difference in the quartz which correlates with the known lack of gold in the quartz vein at the uppermost, carbonate hosted level 4.

Brusson quartz types

To facilitate comparison between these complex decrepitation curves, each curve was deconvolved to determine the component skewed gaussian populations which combine to generate the overall result. These data samples can comprise between 3 and 5 sub-populations. The peak temperature of the fitted peaks is summarized in the following table.  The curve fitting and some of the data are shown here.

The complexity of these samples with (often) 5 component populations is unusual and interesting. It is also unusual to be able to distinguish a population such as Peak4 with a temperature around 560 C, which is unusually close to the inversion-related peak at 600 C.



Component population temperatures of each sample at Brusson
Run Sample Number
Peak1
Peak2 Peak3 Peak4 Peak5
h2036 1954A _ 438 492 556 598
h2037 1954B 272 396 458 568 598
h2038 1954C 242 418 460 574 598 Lowest adit level
h2039 1954D 296 462 _ 572 598 Location IT6
h2040 1954E 282 418 _ 556 598
h2041 1954F _ 398 496 556 594
h2042 1954G 286 440 500 558 594








h2043 1955A _ 460 508 _ 596
h2044 1955B 272 460 _ 564 598
h2045 1955C 304 478 _ 566 598 Mid-level adit
h2046 1955D 262 446 530 _ 598 Location IT7
h2048 1955E 260 426 466 556 594
h2049 1955F _ 460 _ _ 592








h2050 1956A 284 464 _ _ 596
h2051 1956B _ 454 _ _ 592 Upper adit level
h2052 1956C 284 460 _ _ 596 Location IT8








h2053 1957A 260 470 _ 556 598
h2053 1957A 260 420 484 558 598 Carbonate hosted zone
h2054 1957B 262 336 430 _ 600 Location IT9
h2055 1957C 278 446 _ _ 598
h2056 1957D 258 424 494 570 596

Details of the curve fitting procedure and some of the data are here


 This peak temperature data is plotted below, grouped by both the mine level of the sample and also the quartz type. In this plot, the radius of each plotted circle represents the total number of decrepitation counts in that decrepitation peak. Note the absence of green "type 3 quartz" samples from the uppermost (1710m) level.

Brusson decrep summary data

Conclusions

The decrepitation data reveals that there is a significant difference in the fluid inclusion populations in quartz from the uppermost level when compared with the quartz samples from the 3 lower levels. This observation can be used to define a model for the formation of the Fenilia quartz vein which explains the lack of gold where this vein is hosted by carbonate rocks.

Brusson model section

The Fenilia auriferous quartz vein at Brusson was formed from auriferous fluids coming from the basement, in which the Au is transported as a HS- complex, as shown by L.W. Diamond.  This was not, however, a continuous steady flow and the flow was episodic.

During periods of high fluid upflow rates, the effect of the weak fluid inflow from the host rock units was minimal. The vein-flow fluid temperature remained high and there was little chemical change so the gold present remained in solution and passed through the section without being deposited while type 1 and type 2 quartz was deposited. 


During periods of low fluid upflow rate, the inflow of fluids from the paragneiss host rock unit mixed with the basement sourced fluid and lowered the temperature of the vein-flow fluid. This resulted in phase separation of the CO2 rich fluid into an almost pure CO2 phase and an aqueous dominated phase, with gold partitioning almost completely into the aqueous phase. The gold enriched aqueous fluid gave rise to auriferous quartz deposition and type 3 quartz containing few or no CO2 rich fluid inclusions. At the upper level 4, the stratigraphic inflow fluid from the marble and serpentinite has a high pH, possibly greater than 10. Mixing of this fluid with that in the vein increases the pH, which increases the solubility of the Au(HS)-2 complex and also increases the solubility of silica, despite any temperature decrease. Consequently the quartz at this upper level lacks gold and also lacks type 3 quartz deposition. It is this change in pH caused by mixing with high pH stratigraphic inflow fluids that stops the deposition of gold in the vein at this location.

Diamond also noted that the rock alteration halo adjacent to the vein is frequently very thin, only a few cm thick. This is inconsistent with his assumption of wall rock reaction being the cause of depositional control. However, the model proposed here with gold and quartz deposition being controlled by fluid mixing with fluids ingressing from the host strata, is entirely consistent with the observed minimal wall rock alteration halo adjacent to the vein.

The fluid system at Brusson was CO2 rich and the fluid inclusions show many differing populations which undoubtedly reflect a complex fluid history of multiple events which contribute to the complex zonation of the quartz.  Despite this complexity of quartz deposition, the decrepitation data provides key information to understand just why the gold within the vein is controlled by the type of host rock.




Complete Brusson decrepitation data plots

Brusson, Lowest level adit entrance   ~1560m altitude

Most samples from the lower adit entrance show intense low temperature decrepitation due to abundant CO2 rich fluid inclusions. But the quartz is zoned and some samples lack CO2 rich inclusions.




















H2036 - 2042 Sample# 1954A-G     0.5gm -420+200u
Brusson lowest adit entrance and into adit.  GPS location  IT6



Brusson mid-level adit entrance - 1648 level.

Some but not all samples have low temperature CO2 caused decrepitation peaks. Note the complexity of the many inclusion populations between 400 and 560 C. This quartz is the product of numerous different fluid events and it is incorrect to think of it as a single rock even though it is a single mineral phase.




















H2043-2049 Sample# 1955A-F    0.5gm -420+200u
Brusson next level up, 1660m alt. (1648 level)    GPS location IT7



Brusson upper level adit entrance

Low temperature CO2 caused decrepitation is still present at the upper adit entrance.




















H2050-2052 Sample# 1956A-C     0.5g -420+200u
Brusson mine, 2 levels up (poor fix 1660m)    GPS location  IT8


Brusson   Carbonate hosted quartz at ~ 1740 m altitude, non Au mineralised.

Although outside the economically  mineralized Au zone, low temperature CO2 caused decrepitation is still prominent.
This is still quite close to the ore zone and perhaps the CO2 is part of a fairly large halo around the ore zone.





















H2053-2056 Sample# 1957A-D     0.5g -420+200u
Brusson mine, carbonate hosted upper zone,  GPS location    IT9 1740m RL, No Au here



Background samples

These regional samples tend to show an absence of the low temperature peak indicating a general, but not complete, absence of CO2 in unmineralised samples.





















H2032 Sample# 1952      0.5gm -420+200u      coarse very milky white qtz
En Route  to brusson, italy IT4 fuchsite qtz magnesite quarry altd serpentinite























H2033- 2035  Sample# 1953A,B,C      0.5gm -420+200u    coarse milky white qtz
Mae village, river section, near Brusson IT5




References

Mesothermal  gold lodes in the North-western alps: A review of genetic constraints from radiogenic isotopes.
Thomas Pettke, Larryn W Diamond and Jan D Kramers
Eur. J. Mineral.,  2000,  v12,  213-230.
www.geo.unibe.ch/diamond/.../Pettke,Diamond,Kramers_2000.pdf

Fluid inclusion evidence for P-V-T-X evolution of hydrothermal solutions in late alpine gold-quartz veins at Brusson, Val d'ayas, northwest Italian alps.
Larryn W. Diamond
Am. J. Science, v290, Oct 1990, 912-958
www.geo.unibe.ch/diamond/publications/Diamond_1990.pdf

Oligocene gold quartz veins at Brusson, NW Alps; Sr isotopes trace the source of ore-bearing fluid to ore a 10-km depth
Thomas Pettke and Larryn W. Diamond
Economic Geology, Jul 1997; 92: 389 - 406.

Solubility of gold in NaCl and H2S bearing aqueous solutions at 250 - 350 C.
Ken-Ichiro Hayashi and Hiroshi Ohmoto
Geochimica et Cosmochimica Acta, August 1991  V55 #8,  2111-2126


Details of the curve fitting procedure and some of the data are here

Sample Descriptions

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