Rapid fluid inclusion data
for exploration (decrepitation)
A suite of samples was collected from the Tanco pegmatite mine during an organised visit. A large number of these samples were collected from surface waste dumps and their actual location and geological context are not known precisely. Other samples were collected from the underground mine workings, still active at the time of the visit. These samples have location and geological context information.
A description of the Tanco deposit is in:
Petrology and mineralization of the Tanco rare-element
pegmatite, southeastern Manitoba (field trip
BY: Petr Cerny, T.S. Ercit and P.T. Vanstone
Geological Association of Canada, Annual meeting 1996, Winnipeg, Manitoba (field-trip guidebook)
A mine stop map with
sample collection locations is here (opens in a separate
Samples from the Tanco pegmatite show remarkably high
decrepitation at very low temperatures (200 to 300C) indicating
the presence of very high gas contents (CO2 + CH4)
in the fluid inclusions. Although CH4 has been found in
inclusions at Tanco by R. Thomas, his samples were from near-wall
locations and the CH4 may have originated from the surrounding
country rock. The decrepitation data shows that the highest gas
contents occur in or near the core zone of the pegmatites, where
CH4 is probably minimal and it is therefore concluded
that CO2 is a prominent constituent of the primary
Tanco pegmatite formation fluids. Such CO2 rich fluids
do occur in other pegmatites documented
here, but to a much lesser extent than at Tanco.
Although there are interesting variations in decrepitation
between 350 and 550 C, it is not possible to interpret the origin
or significance of these changes based on this data.
Feldspar samples can show decrepitation, such as sample 1374D,
but most feldspar samples analysed in this study show very little
or no decrepitation which does not match the decrepitation from
co-existing quartz samples. It is unclear why feldspar samples
lack fluid inclusions or have trapped such different inclusion
populations to the adjacent quartz, when both minerals presumably
formed from the same fluid.
Pollucite (sample 1385H) did show intense decrepitation, though
it lacked CO2 rich fluids. Insufficient monomineralic
pollucite samples were available to interpret this result.
Pegmatites, and specifically the quartz within them, are suitable
materials for acoustic decrepitation analysis, and such
decrepitation analyses may aid in exploration for economically
Samples 1372 to 1375 were collected from waste dumps on the
surface near the mill.
Quartz samples from Tanco usually show intense decrepitation at
low temperatures between 200 and 300 C indicating the presence of
abundant gas rich inclusions with high gas partial pressures. Work
by Rainer Thomas has shown that CH4 is common in fluid
inclusion fluids at Tanco and decrepitation can only show the
combined effect of ( CO2 + CH4 ) contents.
However it seems that the gas content in the fluids at Tanco is
far higher than the estimates of 1-3 mol % (combined) reported in